CDWGN - BUTYL ACETATE
- MSDS: CDWGN
- Manufacturer: FISHER SCIENTIFIC
- Product Name: BUTYL ACETATE
- National Stock Number: 6810-00N040236
Product Identification
Product ID:BUTYL ACETATE
MSDS Date:07/16/1992
FSC:6810
NIIN:00N040236
MSDS Number: CDWGN
Responsible Party
FAIR LAWN, NJ 07410
US
Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)
Info Phone: 201-796-7100
Cage: 1B464
Contractor
Telephone: 201-796-7100
Cage: 1B464
Ingredients
CARTRIDGES. 1500 PPM-ANY SUPP-AIR RESP, ANY
RTECS: 9999999ZZ
FLOW MODE. 7500 PPM-ANY AIR-PURIFYING FULL
RTECS: 9999999ZZ
ORG VAP CANISTER, ANY SCBA W/FULL FACEPIECE, ANY
RTECS: 9999999ZZ
AIR RESP W/FULL FACEPIECE & OPERATED IN
RTECS: 9999999ZZ
FULL FACEPIECE RESP (GAS MASK)
RTECS: 9999999ZZ
TYPE SCBA. FOR A COMPLETE LIST OF RESPIRATORS
RTECS: 9999999ZZ
WELL AFTER FIRE IS OUT. STAY AWAY FROM
RTECS: 9999999ZZ
UNMANNED HOSE HOLDER/MONITOR NOZZ; IF THIS IS
RTECS: 9999999ZZ
IN CASE OF RISING SOUND FROM VENTING SFTY
RTECS: 9999999ZZ
MILE IN ALL DIRECTIONS IF TANK, RAIL CAR/TANK TRUCK
RTECS: 9999999ZZ
STOPPED; USE WATER IN FLOODING AMTS AS FOG. SOLID
RTECS: 9999999ZZ
OF WATER. AVOID BRTHG TOX VAPS. KEEP UPWIND. WATER
RTECS: 9999999ZZ
ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA) LD50
CAS: 123-86-4
RTECS: AF7350000
Fraction By Weight: 100%
OSHA PEL 150 PPM
ACGIH TLV: 150 PPM/200STEL
EPA Report Quantity: 5000 LBS
DOT Report Quantity: 5000 LBS
ABNORM WERE OBSERVED IN STUDY OF PREGNANT RATS
RTECS: 9999999ZZ
OTHER MORPHOLOGICAL VARIATIONS WERE REPORTED. SKIN
RTECS: 9999999ZZ
DERM HAS BEEN REPORTED IN FACTORY WORKER. EYE
RTECS: 9999999ZZ
CASES OF VACUOLAR KERATOPATHY HAVE OCCURRED AMONG
RTECS: 9999999ZZ
NO DATA AVAILABLE. TARGET
RTECS: 9999999ZZ
IF CONSCIOUS & NOT CONVULSING,
RTECS: 9999999ZZ
(IF VOMIT OCCURS, KEEP HEAD BELOW HIPS TO PVNT
RTECS: 9999999ZZ
ACTIVATED CHARCOAL. IN PATIENTS W/DEPRESSED RESP/IF
RTECS: 9999999ZZ
CAUTIOUSLY. TREAT SYMPTOMATICALLY & SUPPORTIVELY.
RTECS: 9999999ZZ
NO SPECIFIC
RTECS: 9999999ZZ
HAZ AREA. KEEP UNNEC PEOPLE AWAY; ISOLATE HAZ
RTECS: 9999999ZZ
WHICH MEET BONDING & GROUNDING GUIDELINES
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT/NARCOTIC/HIGHLY TOX.
10,000 IMMED DANGEROUS TO LIFE/HLTH. VAP MAY CAUSE IRRIT OF UPPER
RESP TRACT W/COUGH & SHORTNESS OF BRTH. IN HUMANS, 200 PPM
IRRITATED NOSE & THROAT W/MORE SEV IRRIT OCCURRING AT 300 PPM.
HIGH CONCS MAY CAUSE NARCOS W/HDCH, NAUS, DIZZ, WEAK, DULLNESS,
DROW & UNCON. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: IN ANIMAL STUDIES NARCOS & DEATH
OCCURRED AT HIGH CONCS. SKIN: MAY CAUSE IRRIT W/REDNESS & DRYING.
IF SUFFICIENT AMTS ARE ABSORBED THRU SKIN, SYSTEMIC EFTS MAY OCCUR.
EYE: VAP CAUSES IRRIT I N HUMANS AT 200-300 PPM. AT CONCS >3300PPM,
TEARING & HYPEREMIA OF CONJ MAY OCCUR. APPLICATION OF LIQ (SUP DAT)
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING KIDNEY,
LIVER, OR RESPIRATORY DISEASE.
First Aid
First Aid:INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF
RESP. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY.
GET MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH
AFFECTE D AREA W/SOAP & WATER UNTIL NO EVIDENCEOF CHEM REMAINS
(15-20 MIN). GET MED ATTN IMMED. EYE: WASH IMMED W/LGE AMTS OF
WATER UNTIL NO EVIDENCE OF CHEM REMAINS (15-20 MIN). GET MED ATTN
IMMED. (ING 7)
Fire Fighting
Flash Point Method:CC
Flash Point:72.0F,22.2C
Lower Limits:1.7%
Upper Limits:7.6%
Extinguishing Media:DRY CHEM, CARBON DIOXIDE, WATER
SPRAY/ALCOHOL-RESIST FOAM. FOR LGE FIRES, USE WATER SPRAY,
FOG/ALCOHOL-RESIST FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
MOVE CONTR FROM FIRE AREA IF W/OUT RISK. APPLY COOLING WATER TO
SIDES OF CONTRS EXPOSED TO FLAMES UNTIL(ING 20)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ & MOD EXPLO HAZ WHEN
EXPOS TO HEAT/FLAME. VAPS HVR/AIR, MAY TRAVEL CONSIDERABLE DIST TO
IGNIT SOURCE & FLASH BACK. VAP-AIR MIX EXPLO >FL PT.
Accidental Release
Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF W/OUT
RISK. USE WATER SPRAY TO REDUCE VAPS. SML SPILL: TAKE UP
W/SAND/OTHER ABSORB MATL & PLACE INTO CONTRS FOR LATER DISP. LGE
SPILL: DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO SMKNG,
FLAMES/FLARES IN (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:STORE I/A/W 29 CFR 1910.106. STORE
AWAY FROM INCOMPATIBLE MATLS. VAPS MAY BE EXPLO & POIS; DO NOT
ALLOW UNNEC PERS IN AREA. DO NOT OVERHEAT CONTRS.
Other Precautions:CONTRS MAY VIOLENTLY RUPTURE & TRAVEL CONSIDERABLE
DIST IN HEAT OF FIRE. OBSERVE ALL FED, STATE & LOC REGS WHEN
STORING. SUBSTANCES W/LOW ELECTROCONDUCTIVITY, WHICH MAY BE IGNITED
BY ELECTROSTATIC SPK S, SHOULD BE STORED IN CONTRS (ING 13)
Exposure Controls
Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM
LEVELS FOUND IN WORK PLACE, MUST NOT EXCEED WORKING LIMS OF RESP &
BE NIOSH APPRVD: 1000 PPM-ANY POWERED AIR-PURIFYING RESP W/ORG VAP
CARTRIDGES, ANY CHE M CARTRIDGE RESP W/ORG VAP (ING 14)
Ventilation:PROCESS ENCLOSURE VENTILATION RECOMMENDED TO MEET PUBLISHED
EXPOS LIMITS. VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT ANY SKIN CONT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: TO RABBIT EYES CAUSED SUPERFICIAL REVERSIBLE INJURY.
INGEST: MAY CAUSE SORE THROAT, ABDOM PAIN, NAUS & CNS EFTS (HDCH,
WEAK, DIZZ, DROW & UNCON). CHRONIC: INHAL: RPTD EXPOS HAVE RSLTD
IN WEAK, LOSS OF WT, RENAL CHANGES & MINOR BLOOD CHANGES. MATERNAL
TOX, FETAL TOX & INCRD INCIDENCE OF SKELETAL (ING 2)
Chemical Properties
Boiling Pt:B.P. Text:261F,127C
Melt/Freeze Pt:M.P/F.P Text:-108F,-78C
Vapor Pres:10 @ 20C
Vapor Density:4.0
Spec Gravity:0.8825
Evaporation Rate & Reference:5.8 (CCL4=1)
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:COLORLESS LIQUID WITH A FRUITY ODOR
Percent Volatiles by Volume:100
Stability
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG ALKALIES, NITRATES, STRONG OXIDIZERS, PLASTICS AND
RESINS, POTASSIUM TERT-BUTOXIDE.
Stability Condition to Avoid:AVOID CONTACT WITH HEAT, SPARKS, FLAMES,
OR OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCT MAY
INCLUDE TOXIC OXIDES OF CARBON.
Disposal
Waste Disposal Methods:DISP MUST BE I/A/W STDS APPLIC TO GENERATORS OF
HAZ WASTE, 40 CFR 262. EPA HAZ WASTE # D001. 100 LB CERCLA SECTION
103 REPORTABLE QTY. OBSERVE ALL FED, STATE & LOC REGS WHEN DISP.
FOR ASSIST, CONT DIS TRICT DIRECTOR OF ENVIRONMENTAL PROT AGENCY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.